727 research outputs found
Three-antenna two-dimensional imaging correlation radiometer: concept and preliminary results
Peer ReviewedPostprint (published version
Matter-antimatter asymmetry without departure from thermal equilibrium
We explore the possibility of baryogenesis without departure from thermal
equilibrium. A possible scenario is found, though it contains strong
constraints on the size of the violation () effects and on the role
of the (baryon number) nonconserving interactions which are needed for it.Comment: Revtex, 4page
Characterization of periodic cavitation in an optical tweezer
Microscopic vapor explosions or cavitation bubbles can be generated
periodically in an optical tweezer with a microparticle that partially absorbs
at the trapping laser wavelength. In this work we measure the size distribution
and the production rate of cavitation bubbles for microparticles with a
diameter of 3 m using high speed video recording and a fast photodiode. We
find that there is a lower bound for the maximum bubble radius m which can be explained in terms of the microparticle size. More than
of the measured are in the range between 2 and 6 m,
while the same percentage of the measured individual frequencies or
production rates are between 10 and 200 Hz. The photodiode signal yields an
upper bound for the lifetime of the bubbles, which is at most twice the value
predicted by the Rayleigh equation. We also report empirical relations between
, and the bubble lifetimes.Comment: 5 pages, 3 figure
Time evolution of the behaviour of Brazilian legislative Representatives using a complex network approach
The follow up of Representative behavior after elections is imperative for a
democratic Representative system, at the very least to punish betrayal with no
re-election. Our goal was to show how to follow Representatives' and how to
show behavior in real situations and observe trends in political crises
including the onset of game changing political instabilities. We used
correlation and correlation distance matrices of Brazilian Representative votes
during four presidential terms. Re-ordering these matrices with Minimal
Spanning Trees displays the dynamical formation of clusters for the sixteen
year period, which includes one Presidential impeachment. The reordered
matrices, colored by correlation strength and by the parties clearly show the
origin of observed clusters and their evolution over time. When large clusters
provide government support cluster breaks, political instability arises, which
could lead to an impeachment, a trend we observed three years before the
Brazilian President was impeached. We believe this method could be applied to
foresee other political storms.Comment: 11 pages, 4 Figure
Cosmic Neutrinos as a Window to Departures from Special Relativity
We review the peculiarities that make neutrinos very special cosmic messengers in high-energy astrophysics, and, in particular, to provide possible indications of deviations from special relativity, as it is suggested theoretically by quantum gravity models. In this respect, we examine the effects that one could expect in the production, propagation, and detection of neutrinos, not only in the well-studied scenario of Lorentz Invariance Violation, but also in models which maintain, but deform, the relativity principle, such as those considered in the framework of Doubly Special Relativity. We discuss the challenges and the promising future prospects offered by this phenomenological window to physics beyond special relativity
Dynamic Kinetic Resolution of Hetero biaryl Ketones by Zinc- Catalyzed Asymmetr ic Hydrosil ylation
Adiastereo-
and
highly
enantioselective
dynamic
kinetic
resolution
(DKR)
of configurationally
labile
hetero-
biaryl
ketones
is described.
The
DKR
proceeds
by zinc-
catalyze
dhydrosilylation
of the carbonyl
group
,thus leading
to
secondary
alcohols
bearing
axial
and
central
chirality
.The
strategy
relies
on the labilization
of the stereogenic
axis
that
takes
place
thanks
to aLewis
acid–base
interaction
between
anitrogen
atom
in the heterocycle
and
the ketone
carbonyl
group
.The synthetic
utility
of the methodology
is demonstrated
through
stereospecific
transformations
into either
N,N-ligands
or appealing
axially
chiral,
bifunctional
thiourea
organocata-
lysts.Ministerio de Ciencia e Innovación (Grants CTQ2016-76908-C2-1-P, CTQ2016-76908-C2-2-P, contract RYC-2013-12585)European FEDER FundsJunta de AndalucÃa (Grant 2012/FQM 10787)European Union - Marie SkÅ‚odowska-Curie (COFUND—Grant Agreement n 8 8 291780
Shake-up effects and intermolecular tunneling in C60 ions
4 págs.;1 fig.; 3 tabs. ; Rapid CommunicationsThe multiplet structure induced by the Coulomb interactions in C60 n- (n=1-12) is analyzed. The lowest partially occupied molecular orbital gives rise to a set of levels that fill a relatively wide band (2-3 eV). A large (∼1 eV) intramolecular effective repulsion is found. The anions are also shown to be highly polarizable. The optical-absorption and photoemission spectra are calculated. The probability of exciting the molecule upon the addition or removal of one electron is shown to be significant, and this effect may give rise to the insulating behavior of K4C60. The role of intermolecular interactions in suppressing the net repulsion within the C60 molecules is discussed. © 1994 The American Physical Society.Peer Reviewe
Contaminación de suelos y aguas subterraneas por vertidos industriales
In the industrialised countries, soil and groundwater contamination caused by uncontrolled spills of industrial wastes is one of the most critical environmental problem, because its removal is expensive and difficult to carry out, and the effects persist during many years. In Spain this problem is especially notorious due to an inadequate management policy derived from the absence of coordination between the different involved sectors. The treatment installations are inot enough, so it has produced spillings in streams and soils or its storage in uncontrolled landfillings.The experiences and guidelines of the Environmental Protection Agency from United States have served to the industrialised countries to evaluate this kind of contamination. This methodology is based on its identification and delimitation in soil and groundwater. After the design of a monitoring and control program it can be established the correcting measures. For this reason it is important to know the transfer processes of pollutants between the saturated and not saturated medium, for this reason it is essential the use of geochemical and geophysical methods and their combination with hydrogeological methods.In Spain, this kind of studies is only carried out recently. A case history is the contamination of the alluvial aquifer of the Besos river (Barcelona) by Cr-VI and other heavy metals and organic microcontaminants
- …